Synthesis and Characterization of Epoxy Resins-Modified Waterborne Polyurethane Emulsion
Chenhan Zhuang
School of Chemical Engineering, East China University of Science and Technology, 200237 Shanghai, China.
Weilan Xue *
School of Chemical Engineering, East China University of Science and Technology, 200237 Shanghai, China.
Zuoxiang Zeng
School of Chemical Engineering, East China University of Science and Technology, 200237 Shanghai, China.
*Author to whom correspondence should be addressed.
Abstract
Aqueous polyurethane emulsion was prepared with diphenylmethane diisocyanate (MDI), polybutylene adipate diol (PBA-1000) as main raw materials and 2, 2-dihydroxymethyl propionic acid (DMPA) as hydrophilic chain extender. On this basis, epoxy resin E-44 was introduced to modify the polyurethane prepolymer, and epoxy resin modified waterborne polyurethane emulsion was obtained. In order to obtain better performance waterborne polyurethane, the effect of DMPA content、the amount of epoxy resin added and modification method on the properties of polyurethane was discussed. The results show that when the DMPA content is 4wt%, the overall performance of the emulsion and the film is the best. And the addition of epoxy resin significantly improves the water resistance, solvent resistance and tensile strength of the waterborne polyurethane film, and its hardness and thermal stability are also improved to a certain extent. When the amount of epoxy resin added is 8wt%, the storage stability decreases significantly, the suitable amount of epoxy resin added is 6wt%. The overall performance of the film obtained by chemical modification is better than that of physical modification.
Keywords: Waterborne polyurethane, epoxy resin, modification